French heavyweights Paris Saint-Germain were drawn against 2012 winners Chelsea for the third straight season, while Bayern Munich will meet last year's finalists Juventus.
Record 10-time winners Real Madrid will face Roma while Manchester City will meet Ukrainians Dynamo Kiev for a place in the quarter-finals.
The draw was carried out at UEFA headquarters in Nyon. The games will be between February 16 and March 16.
Complete draw for the UEFA Champions League
Gent (BEL) v VfL Wolfsburg (GER)
AS Roma (ITA) v Real Madrid (ESP)
Paris Saint-Germain (FRA) v Chelsea (ENG)
Arsenal (ENG) v Barcelona (ESP)
Juventus (ITA) v Bayern Munich (GER)
PSV Eindhoven (NED) v Atletico Madrid (ESP)
Benfica (POR) v Zenit St Petersburg (RUS)
Dynamo Kiev (UKR) v Manchester City (ENG)
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