Both teams have made perfect starts to their respective seasons, collecting maximum points from their five league games so far while PSG have also lifted the Trophee des Champions.
The French outfit have been knocked out in the last 16 of this competition in each of the past two seasons, though, whereas Liverpool made it all the way to the final last term before being beaten by Real Madrid.
Make sure you don't miss a moment of the action courtesy of our minute-by-minute updates below.
OFFICIAL LINE-UPS
LIVERPOOL: Alisson; Alexander-Arnold, Van Dijk, Gomez, Robertson; Milner, Henderson, Wijnaldum; Salah, Sturridge, Mane
LIVERPOOL SUBS: Mignolet, Fabinho, Keita, Firmino, Moreno, Shaqiri, Matip
PSG: Areola; Meunier, Silva, Kimpembe, Bernat; Rabiot, Marquinhos, Di Maria; Mbappe, Cavani, Neymar
PSG SUBS: Kehrer, Choupo-Moting, Diarra, Draxler, Nkunku, Nsoki, Cibois
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