Barcelona have already booked their spot in the round of 16 as winners of Group B.
Tottenham, meanwhile, sit second in the section, level on seven points with third-placed Inter Milan.
Spurs must match Inter's result against PSV Eindhoven in order to advance to the next round of the competition.
Stay tuned for live minute-by-minute updates from Camp Nou.
OFFICIAL LINE-UPS
BARCELONA (4-3-3): Cillessen; Semedo, Lenglet, Vermaelen, Miranda; Alena, Rakitic, Arthur; Coutinho, Munir, Dembele
TOTTENHAM HOTSPUR (4-2-3-1): Lloris; Walker-Peters, Alderweireld, Vertonghen, Rose; Winks, Sissoko; Eriksen, Alli, Son; Kane
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